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Math

Math Snap

PROBLEM

Which of the following is the correct expression for the KspK_{s p} of MgCO3\mathrm{MgCO}_{3} ?
Ksp=[Mg2+][CO32]\mathrm{K}_{\mathrm{sp}}=\left[\mathrm{Mg}^{2+}\right]\left[\mathrm{CO}_{3}^{2-}\right]
Ksp=1[Mg2+[CO32]\mathrm{K}_{\mathrm{sp}}=\frac{1}{\left[\mathrm{Mg}^{2+} \mid\left[\mathrm{CO}_{3}^{2}\right]\right.}
Ksp =[Mg2+][CO2]3\mathbb{K}_{\text {sp }}=\left[\mathrm{Mg}^{2+}\right]\left[\mathrm{CO}^{2-}\right]^{3}
Ksp =[6012][Mg2+1]\mathbb{K}_{\text {sp }}=\frac{\left[60_{-1}^{2}\right]}{\left[\mathrm{Mg}^{2+1}\right]}
xsp=[Mg2+][C][O32]]\left.\mathrm{x}_{s p}=\left[\mathrm{Mg}^{2+}\right][C]\left[\mathrm{O}_{3}^{2-}\right]\right]

STEP 1

What is this asking?
Which expression correctly shows how much magnesium carbonate dissolves in a solution?
Watch out!
Don't mix up the Ksp expression with other equilibrium expressions! Ksp is specifically for how much a solid dissolves.

STEP 2

1. Understand Ksp
2. Write the balanced dissolution equation
3. Build the Ksp expression

STEP 3

Ksp, the solubility product constant, tells us how much a solid dissolves into its ions in a saturated solution.
A bigger Ksp means more dissolving!
It's like a popularity contest for dissolved ions!

STEP 4

Ksp is all about equilibrium.
When the solid is dissolving as fast as the ions are coming back together, we've hit equilibrium, and Ksp describes that balance.

STEP 5

We're dealing with magnesium carbonate, MgCO3(s)_{(s)}.
When it dissolves, it breaks into its ions: magnesium, Mg2+(aq)_{(aq)}, and carbonate, CO32−(aq)_{(aq)}.

STEP 6

The balanced equation looks like this:
MgCO3(s)Mg2+(aq)+CO32(aq) \text{MgCO}_3(s) \rightleftharpoons \text{Mg}^{2+}(aq) + \text{CO}_3^{2-}(aq) See? One magnesium carbonate breaks down into one magnesium ion and one carbonate ion.
Perfectly balanced, as all things should be!

STEP 7

The Ksp expression is built by multiplying the concentrations of the dissolved ions, each raised to the power of its coefficient in the balanced equation.

STEP 8

From our balanced equation, both Mg2+ and CO32− have a coefficient of 1.
So, our Ksp expression is:
Ksp=[Mg2+]1[CO32]1 K_{sp} = [\text{Mg}^{2+}]^1 \cdot [\text{CO}_3^{2-}]^1 We don't include the solid MgCO3(s)_{(s)} in the Ksp expression because its concentration is constant.

STEP 9

Since anything raised to the power of 1 is just itself, we can simplify to:
Ksp=[Mg2+][CO32] K_{sp} = [\text{Mg}^{2+}] \cdot [\text{CO}_3^{2-}]

SOLUTION

The correct expression for the Ksp of MgCO3 is Ksp=[Mg2+][CO32] K_{sp} = [\text{Mg}^{2+}] \cdot [\text{CO}_3^{2-}] , which is the first option.

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