Math  /  Algebra

QuestionPractice 8 How much heat is evolved when 266 g of white phosphorus (P4P_4) burns in air?
P4(s)+5O2(g)undefinedΔP4O10(s)P_4(s) + 5O_2(g) \xrightarrow{\Delta} P_4O_{10}(s) ΔH=3013\Delta H = -3013 kJ

Studdy Solution

STEP 1

1. The chemical reaction given is P4(s)+5O2(g)P4O10(s) P_4(s) + 5O_2(g) \rightarrow P_4O_{10}(s) .
2. The enthalpy change (ΔH\Delta H) for the reaction is 3013-3013 kJ, indicating that the reaction is exothermic.
3. We need to calculate the heat evolved when 266 g of P4 P_4 burns.
4. The molar mass of P4 P_4 is needed to convert grams to moles.

STEP 2

1. Calculate the molar mass of P4 P_4 .
2. Convert the mass of P4 P_4 to moles.
3. Use the stoichiometry of the reaction to find the heat evolved.

STEP 3

Calculate the molar mass of P4 P_4 .
The atomic mass of phosphorus (P) is approximately 31 g/mol. Since P4 P_4 consists of 4 phosphorus atoms, the molar mass of P4 P_4 is:
Molar mass of P4=4×31g/mol=124g/mol \text{Molar mass of } P_4 = 4 \times 31 \, \text{g/mol} = 124 \, \text{g/mol}

STEP 4

Convert the mass of P4 P_4 to moles.
Given mass of P4 P_4 is 266 g. Using the molar mass calculated:
Moles of P4=266g124g/mol \text{Moles of } P_4 = \frac{266 \, \text{g}}{124 \, \text{g/mol}}
Moles of P4=2.145mol \text{Moles of } P_4 = 2.145 \, \text{mol}

STEP 5

Use the stoichiometry of the reaction to find the heat evolved.
The reaction shows that 1 mole of P4 P_4 releases 3013 kJ of heat. Therefore, for 2.145 moles of P4 P_4 :
Heat evolved=2.145mol×(3013kJ/mol) \text{Heat evolved} = 2.145 \, \text{mol} \times (-3013 \, \text{kJ/mol})
Heat evolved=6463.785kJ \text{Heat evolved} = -6463.785 \, \text{kJ}
The negative sign indicates that the heat is evolved (released).
The heat evolved when 266 g of P4 P_4 burns in air is approximately:
6463.785kJ \boxed{-6463.785 \, \text{kJ}}

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