Math  /  Data & Statistics

QuestionOne cup (250. mL) of coffee contains 125 mg of caffeine. One cup of tea has 0.100 g of caffeine. A can of Diet Coke ( 355 mL ) contains 50.mg50 . \mathrm{mg} of caffeine, and a can of Surge (355 mL)(355 \mathrm{~mL}) contains about 65 mg of caffeine. Caffeine is C8H10 N4O2\mathrm{C}_{8} \mathrm{H}_{10} \mathrm{~N}_{4} \mathrm{O}_{2}. a. Which drink has the most caffeine per milliliter? Show how you arrived at your conclusion. (3 points) b. Calculate the molarity of caffeine in the drink you chose in part a. (5 points)

Studdy Solution

STEP 1

What is this asking? Which drink has the highest caffeine concentration and what is that concentration in molarity? Watch out! The caffeine amounts are given in different units (mg and g), so we need to be careful with unit conversions!
Also, remember molarity is moles per liter, not moles per milliliter.

STEP 2

1. Calculate Caffeine Concentration per Milliliter
2. Determine the Drink with the Highest Concentration
3. Calculate the Molar Mass of Caffeine
4. Calculate the Molarity

STEP 3

Let's **calculate** the caffeine concentration for each drink in milligrams of caffeine per milliliter of drink.
This will help us compare them directly.
For coffee, we have 125 mg250 mL\frac{125 \text{ mg}}{250 \text{ mL}}.

STEP 4

Dividing gives us 0.500mgmL0.500 \frac{\text{mg}}{\text{mL}} for coffee.
See how we kept the units with the number?
That's super important so we don't get confused later!

STEP 5

For tea, we have 0.1000.100 g of caffeine.
Since there are 10001000 mg in 11 g, we multiply 0.100 g1000 mg1 g=100 mg0.100 \text{ g} \cdot \frac{1000 \text{ mg}}{1 \text{ g}} = 100 \text{ mg} of caffeine in one cup of tea.

STEP 6

Now, we can **divide** this by the volume, 250250 mL, to get 100 mg250 mL=0.400mgmL\frac{100 \text{ mg}}{250 \text{ mL}} = 0.400 \frac{\text{mg}}{\text{mL}}.

STEP 7

Diet Coke has 50 mg355 mL0.141mgmL\frac{50 \text{ mg}}{355 \text{ mL}} \approx 0.141 \frac{\text{mg}}{\text{mL}}.
We're rounding to three significant figures here to match the given values.

STEP 8

Finally, Surge has 65 mg355 mL0.183mgmL\frac{65 \text{ mg}}{355 \text{ mL}} \approx 0.183 \frac{\text{mg}}{\text{mL}}.

STEP 9

Comparing the values we just calculated, we see that coffee has the **highest** concentration of caffeine at 0.500mgmL0.500 \frac{\text{mg}}{\text{mL}}.

STEP 10

The formula for caffeine is C8H10 N4O2\mathrm{C}_{8} \mathrm{H}_{10} \mathrm{~N}_{4} \mathrm{O}_{2}.
To **calculate** the molar mass, we'll **add** the atomic masses of all the atoms in one molecule of caffeine.

STEP 11

We have 88 carbon atoms, 1010 hydrogen atoms, 44 nitrogen atoms, and 22 oxygen atoms.
Using the periodic table, we find the molar mass: 812.01gmol+101.01gmol+414.01gmol+216.00gmol8 \cdot 12.01 \frac{\text{g}}{\text{mol}} + 10 \cdot 1.01 \frac{\text{g}}{\text{mol}} + 4 \cdot 14.01 \frac{\text{g}}{\text{mol}} + 2 \cdot 16.00 \frac{\text{g}}{\text{mol}}.

STEP 12

This **sums** to 96.08+10.10+56.04+32.00=194.22gmol96.08 + 10.10 + 56.04 + 32.00 = 194.22 \frac{\text{g}}{\text{mol}}.
So, the molar mass of caffeine is 194.22gmol194.22 \frac{\text{g}}{\text{mol}}.

STEP 13

We found that coffee has 0.500mgmL0.500 \frac{\text{mg}}{\text{mL}} of caffeine.
To **calculate** the molarity, we need the concentration in moles per liter.

STEP 14

First, let's convert milligrams to grams: 0.500mgmL1 g1000 mg=0.000500gmL0.500 \frac{\text{mg}}{\text{mL}} \cdot \frac{1 \text{ g}}{1000 \text{ mg}} = 0.000500 \frac{\text{g}}{\text{mL}}.

STEP 15

Next, convert grams to moles using the molar mass: 0.000500gmL1 mol194.22 g0.00000257molmL0.000500 \frac{\text{g}}{\text{mL}} \cdot \frac{1 \text{ mol}}{194.22 \text{ g}} \approx 0.00000257 \frac{\text{mol}}{\text{mL}}.

STEP 16

Finally, convert milliliters to liters: 0.00000257molmL1000 mL1 L0.00257molL0.00000257 \frac{\text{mol}}{\text{mL}} \cdot \frac{1000 \text{ mL}}{1 \text{ L}} \approx 0.00257 \frac{\text{mol}}{\text{L}}.

STEP 17

Coffee has the highest caffeine concentration at 0.500mgmL0.500 \frac{\text{mg}}{\text{mL}}.
The molarity of caffeine in coffee is approximately 0.002570.00257 M.

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