Math  /  Data & Statistics

QuestionEthylene glycol (C2H6O2)\left(\mathrm{C}_{2} \mathrm{H}_{6} \mathrm{O}_{2}\right) is a molecular compound that is used in many commercial anti-freezes. A water solution of ethylene glycol is used in vehicle radiators to lower its freezing point and thus prevent the water in the radiator from freezing. Calculate the freezing point of a solution of 552 g of ethylene glycol in 892 g of water. Kf=1.86C/m\mathrm{K}_{\mathrm{f}}=1.86^{\circ} \mathrm{C} / \mathrm{m}
Use the following mass numbers: C- 12 H - 1 O-16 Write the final answer in 2 decimal places.

Studdy Solution

STEP 1

1. The formula for freezing point depression is ΔTf=iKfm\Delta T_f = i \cdot K_f \cdot m, where ii is the van't Hoff factor (which is 1 for ethylene glycol, a non-electrolyte), KfK_f is the cryoscopic constant, and mm is the molality of the solution.
2. The molar mass of ethylene glycol (C2H6O2)\left(\mathrm{C}_{2} \mathrm{H}_{6} \mathrm{O}_{2}\right) needs to be calculated.
3. The solution consists of 552 g of ethylene glycol and 892 g of water.

STEP 2

1. Calculate the molar mass of ethylene glycol.
2. Determine the molality of the solution.
3. Calculate the freezing point depression.
4. Determine the new freezing point of the solution.

STEP 3

Calculate the molar mass of ethylene glycol (C2H6O2)\left(\mathrm{C}_{2} \mathrm{H}_{6} \mathrm{O}_{2}\right).
Molar mass=(2×12)+(6×1)+(2×16)=24+6+32=62g/mol\text{Molar mass} = (2 \times 12) + (6 \times 1) + (2 \times 16) = 24 + 6 + 32 = 62 \, \text{g/mol}

STEP 4

Calculate the number of moles of ethylene glycol:
Moles of ethylene glycol=552g62g/mol=8.903mol\text{Moles of ethylene glycol} = \frac{552 \, \text{g}}{62 \, \text{g/mol}} = 8.903 \, \text{mol}

STEP 5

Convert the mass of water to kilograms:
Mass of water=892g1000=0.892kg\text{Mass of water} = \frac{892 \, \text{g}}{1000} = 0.892 \, \text{kg}

STEP 6

Calculate the molality of the solution:
m=8.903mol0.892kg=9.982mol/kgm = \frac{8.903 \, \text{mol}}{0.892 \, \text{kg}} = 9.982 \, \text{mol/kg}

STEP 7

Calculate the freezing point depression using the formula ΔTf=iKfm\Delta T_f = i \cdot K_f \cdot m:
ΔTf=1×1.86C/m×9.982mol/kg=18.57C\Delta T_f = 1 \times 1.86 \, ^\circ \text{C/m} \times 9.982 \, \text{mol/kg} = 18.57 \, ^\circ \text{C}

STEP 8

Determine the new freezing point of the solution. The normal freezing point of water is 0C0^\circ \text{C}:
New freezing point=0C18.57C=18.57C\text{New freezing point} = 0^\circ \text{C} - 18.57^\circ \text{C} = -18.57^\circ \text{C}
The freezing point of the solution is:
18.57C \boxed{-18.57^\circ \text{C}}

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