Math  /  Numbers & Operations

QuestionA chemist dissolves 569.mg569 . \mathrm{mg} of pure barium hydroxide in enough water to make up 120.mL120 . \mathrm{mL} of solution. Calculate the pH of the solution. (The temperature of the solution is 25C25^{\circ} \mathrm{C}.)
Round your answer to 3 significant decimal places. \square ×10\square \times 10 \square\square Start over

Studdy Solution

STEP 1

What is this asking? We need to find how acidic or basic a solution is after some barium hydroxide has been dissolved in water, and we'll measure that with pH! Watch out! Barium hydroxide, Ba(OH)2Ba(OH)_2, provides *two* hydroxide ions when it dissolves.
Don't forget that!

STEP 2

1. Calculate the moles of barium hydroxide.
2. Calculate the concentration of hydroxide ions.
3. Calculate the pOH.
4. Calculate the pH.

STEP 3

We're given the mass of barium hydroxide, which is **569 mg**.
Let's **convert** this to grams because molar mass is usually given in grams per mole.
Remember, there are 1000 mg in 1 g, so we **divide** by 1000: 569 mg1 g1000 mg=0.569 g569 \text{ mg} \cdot \frac{1 \text{ g}}{1000 \text{ mg}} = 0.569 \text{ g}.

STEP 4

Now, we need the **molar mass** of Ba(OH)2Ba(OH)_2.
Looking at the periodic table, we find: Ba = 137.33 g/mol, O = 16.00 g/mol, and H = 1.01 g/mol.
So, the molar mass of Ba(OH)2Ba(OH)_2 is 137.33+2(16.00+1.01)=171.35 g/mol137.33 + 2 \cdot (16.00 + 1.01) = 171.35 \text{ g/mol}.

STEP 5

To find the **moles** of Ba(OH)2Ba(OH)_2, we **divide** the mass by the molar mass: 0.569 g171.35 g/mol=0.00332 mol\frac{0.569 \text{ g}}{171.35 \text{ g/mol}} = 0.00332 \text{ mol}.
Awesome!

STEP 6

Remember, each molecule of Ba(OH)2Ba(OH)_2 releases *two* hydroxide ions (OHOH^-).
So, the **moles of** OH\bf{OH^-} are double the moles of Ba(OH)2Ba(OH)_2: 20.00332 mol=0.00664 mol2 \cdot 0.00332 \text{ mol} = 0.00664 \text{ mol}.

STEP 7

The volume of the solution is **120 mL**.
We need to **convert** this to liters: 120 mL1 L1000 mL=0.120 L120 \text{ mL} \cdot \frac{1 \text{ L}}{1000 \text{ mL}} = 0.120 \text{ L}.

STEP 8

Now we can calculate the **concentration** of OH\bf{OH^-}, which is moles divided by liters: 0.00664 mol0.120 L=0.0553 M\frac{0.00664 \text{ mol}}{0.120 \text{ L}} = 0.0553 \text{ M}.
This "M" stands for molarity!

STEP 9

The pOH is defined as the negative logarithm (base 10) of the hydroxide ion concentration: pOH=log10([OH])pOH = -\log_{10}([OH^-]).

STEP 10

Let's plug in our value: pOH=log10(0.0553)=1.257pOH = -\log_{10}(0.0553) = 1.257.
Looking good!

STEP 11

We know that pH+pOH=14pH + pOH = 14 at 25C25^{\circ} \mathrm{C}.

STEP 12

So, pH=14pOH=141.257=12.743pH = 14 - pOH = 14 - 1.257 = 12.743.
And there we have it!

STEP 13

The pH of the solution is 12.743.

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