Math  /  Data & Statistics

QuestionCalculate ΔGrxn for the following reaction at 298 K. Use the ΔGf values in this table of thermodynamic properties.\text{Calculate } \Delta G_{\mathrm{rxn}} \text{ for the following reaction at 298 K. Use the } \Delta G_{\mathrm{f}}^{\circ} \text{ values in this table of thermodynamic properties.}
Cr2O3(s)+3CO(g)2Cr(s)+3CO2(g)\mathrm{Cr}_{2} \mathrm{O}_{3}(\mathrm{s}) + 3 \mathrm{CO}(\mathrm{g}) \longrightarrow 2 \mathrm{Cr}(\mathrm{s}) + 3 \mathrm{CO}_{2}(\mathrm{g})
ΔGrxn=\Delta G_{\mathrm{rxn}}^{\circ} = \square
 kJ\square \text{ kJ}
\text{Is this reaction spontaneous or nonspontaneous at 298 K?}
\text{nonspontaneous}
\text{spontaneous}
\text{The standard Gibbs free energy of formation values are:}
ΔGf for Cr2O3(s) is 1058.1 kJ/mol\Delta G_{\mathrm{f}}^{\circ} \text{ for } \mathrm{Cr}_{2} \mathrm{O}_{3}(\mathrm{s}) \text{ is } -1058.1 \text{ kJ/mol}
ΔGf for CO(g) is 137.2 kJ/mol\Delta G_{\mathrm{f}}^{\circ} \text{ for } \mathrm{CO}(\mathrm{g}) \text{ is } -137.2 \text{ kJ/mol}
ΔGf for Cr(s) is 0 kJ/mol\Delta G_{\mathrm{f}}^{\circ} \text{ for } \mathrm{Cr}(\mathrm{s}) \text{ is } 0 \text{ kJ/mol}
ΔGf for CO2(g) is 394.4 kJ/mol\Delta G_{\mathrm{f}}^{\circ} \text{ for } \mathrm{CO}_{2}(\mathrm{g}) \text{ is } -394.4 \text{ kJ/mol}

Studdy Solution
Determine if the reaction is spontaneous or nonspontaneous:
Since ΔGrxn=286.5 kJ/mol\Delta G_{\mathrm{rxn}}^{\circ} = 286.5 \text{ kJ/mol} is positive, the reaction is nonspontaneous at 298 K.
The standard Gibbs free energy change for the reaction is:
ΔGrxn=286.5 kJ/mol\Delta G_{\mathrm{rxn}}^{\circ} = \boxed{286.5} \text{ kJ/mol}
The reaction is nonspontaneous at 298 K.

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